Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

1585-16-6 - 2,4,6-Trimethylbenzyl chloride, 98% - alpha(2)-Chloroisodurene - L00423 - Alfa Aesar

L00423 2,4,6-Trimethylbenzyl chloride, 98%

CAS Number
1585-16-6
Synonyms
alpha(2)-Chloroisodurene

Size Price ($) Quantity Availability
25g 81.90
Add to Cart Add to Quote Request View Item

2,4,6-Trimethylbenzyl chloride, 98%

MDL
MFCD00000901
EINECS
216-440-3

Chemical Properties

Formula
C10H13Cl
Formula Weight
168.67
Melting point
37-42°
Boiling Point
114-115°/10mm
Flash Point
106°(222°F)

Literature References

Carboxyl groups can be protected as their 2,4,6-trimethylbenzyl esters by reaction in DMF in the presence of triethylamine. The group can be cleaved by acidolysis (TFA or HBr in AcOH) or hydrogenolysis: Aust. J. Chem., 21, 2831 (1968).

/n

Also reported for the protection of thiols (cysteine), stable to refluxing TFA, unlike 4-methoxybenzyl, but cleavable with HF or TfOH-TFA: Coll. Czech. Chem. Commun., 46, 286 (1981), or Ag(I): Chem. Pharm. Bull., 38, 1551 (1990).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
386678
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware