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1585-16-6 - 2,4,6-Trimethylbenzyl chloride, 98% - alpha(2)-Chloroisodurene - L00423 - Alfa Aesar

L00423 2,4,6-Trimethylbenzyl chloride, 98%

CAS Number
1585-16-6
Synonyms
alpha(2)-Chloroisodurene

Size Price ($) Quantity Availability
5g 24.82
25g 85.18
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2,4,6-Trimethylbenzyl chloride, 98%

MDL
MFCD00000901
EINECS
216-440-3

Chemical Properties

Formula
C10H13Cl
Formula Weight
168.67
Melting point
37-42°
Boiling Point
114-115°/10mm
Flash Point
106°(222°F)

Literature References

Carboxyl groups can be protected as their 2,4,6-trimethylbenzyl esters by reaction in DMF in the presence of triethylamine. The group can be cleaved by acidolysis (TFA or HBr in AcOH) or hydrogenolysis: Aust. J. Chem., 21, 2831 (1968).

/n

Also reported for the protection of thiols (cysteine), stable to refluxing TFA, unlike 4-methoxybenzyl, but cleavable with HF or TfOH-TFA: Coll. Czech. Chem. Commun., 46, 286 (1981), or Ag(I): Chem. Pharm. Bull., 38, 1551 (1990).

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GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
386678
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
No

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