Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

2325-27-1 - Tetraphenylphosphine imide, 97% - N-(Triphenylphosphoranylidene)aniline - L00496 - Alfa Aesar

L00496 Tetraphenylphosphine imide, 97%

CAS Number
2325-27-1
Synonyms
N-(Triphenylphosphoranylidene)aniline

Size Price ($) Quantity Availability
1g 27.99
5g 93.60
Add to Cart Add to Quote Request View Item

Tetraphenylphosphine imide, 97%

MDL
MFCD00003044
EINECS
219-039-1

Chemical Properties

Formula
C24H20NP
Formula Weight
353.40
Melting point
128-132°
Sensitivity
Moisture Sensitive
Solubility
Insoluble in water. Soluble in chloroform 25 mg/mL.

Applications

Has been used as a protected form of aniline for the preparation of monoalkylanilines by alkylation and hydrolysis and as an intermediate for the preparation of isocyanates and isothiocyanates.

Notes

Moisture sensitive. Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

J. Krogh-Moe. The crystal structure of silver tetraborate Ag2O.4B2O3.Acta Cryst.,1965,18,77-81.

C. Dablemont, et al. Investigation of the reactivity of arylamines, organo-hydrazines and tolylisocyanate towards [PW12-xMxO40]n- Keggin anions.Dalton Trans.,2005,(10), 1831-1841.

Has been used as a protected form of aniline for the preparation of monoalkylanilines by alkylation and hydrolysis: Synthesis, 295 (1980).

A Wittig-like reaction with N,N'-diaryl thioureas gives N,N',N"-triarylguanidines: Synth. Commun., 13, 67 (1983).

For a review of the chemistry of iminophosphoranes, see: Synthesis, 469 (1973).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
753032
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • 38092

    PTFE Beaker Cover-Watch Glass;Dia (mm), 30;Fits Beakers, 5-10ml
  • A19994

    Ethyl 2-nitrobenzoate, 97%
  • B23431

    5-Bromo-2-methylbenzotrifluoride, 97+%
  • B20612

    2,2-Dimethyl-3-hexanone, 99%
  • H30935

    3-Amino-1-methyl-1H-pyrazole, 97%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware