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L00541 4-Methoxybenzyl carbazate, 97%

CAS Number
18912-37-3
Synonyms
4-Methoxybenzyl hydrazinocarboxylate
(4-Methoxybenzyl)oxyhydrazine

Stock No. Size Price ($) Quantity Availability
L00541-03 1g 20.60
L00541-06 5g 69.30
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4-Methoxybenzyl carbazate, 97%

MDL
MFCD00042817
EINECS
242-664-6

Chemical Properties

Formula
C9H12N2O3
Formula Weight
196.21
Melting point
75-77°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

It finds its application in the derived azide in N-protection and as a starting material for the azide used to introduce the pMZ-amino protection which is removable under mild hydrolytic conditions.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Jan Legocki, et al. Synthesis and Fungistatic Activity of New Groups of 2,4-Dihydroxythiobenzoyl Derivatives against Phytopathogenic Fungi.J. Agric. Food Chem.,2003,51,(2), 362-368.

Hassan Ali Zamani, et al. Construction of a Highly Selective and Sensitive Ytterbium(III) Membrane Sensor Based on 4-Methoxybenzyl Carbazate as a New Neutral Ionophore.Int. J. Electrochem. Sci.,2013,83429 - 3440.

For use of the derived azide in N-protection, see: Chem. Ber., 95, 1 (1962).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2052164
Harmonized Tariff Code
2928.00
TSCA
No

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