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18912-37-3 - 4-Methoxybenzyl carbazate, 97% - 4-Methoxybenzyl hydrazinocarboxylate - (4-Methoxybenzyl)oxyhydrazine - L00541 - Alfa Aesar

L00541 4-Methoxybenzyl carbazate, 97%

CAS Number
18912-37-3
Synonyms
4-Methoxybenzyl hydrazinocarboxylate
(4-Methoxybenzyl)oxyhydrazine

Size Price ($) Quantity Availability
1g 21.60
5g 73.90
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4-Methoxybenzyl carbazate, 97%

MDL
MFCD00042817
EINECS
242-664-6

Chemical Properties

Formula
C9H12N2O3
Formula Weight
196.21
Melting point
75-77°
Solubility
Insoluble in water.

Applications

It finds its application in the derived azide in N-protection and as a starting material for the azide used to introduce the pMZ-amino protection which is removable under mild hydrolytic conditions.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Jan Legocki, et al. Synthesis and Fungistatic Activity of New Groups of 2,4-Dihydroxythiobenzoyl Derivatives against Phytopathogenic Fungi.J. Agric. Food Chem.,2003,51,(2), 362-368.

Hassan Ali Zamani, et al. Construction of a Highly Selective and Sensitive Ytterbium(III) Membrane Sensor Based on 4-Methoxybenzyl Carbazate as a New Neutral Ionophore.Int. J. Electrochem. Sci.,2013,83429 - 3440.

For use of the derived azide in N-protection, see: Chem. Ber., 95, 1 (1962).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2052164
Harmonized Tariff Code
2928.00
TSCA
No

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