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20082-71-7 - Chlorodimethyl(pentafluorophenyl)silane, 96% - Flophemesyl chloride - Pentafluorophenyldimethylsilyl chloride - L00550 - Alfa Aesar

L00550 Chlorodimethyl(pentafluorophenyl)silane, 96%

CAS Number
20082-71-7
Synonyms
Flophemesyl chloride
Pentafluorophenyldimethylsilyl chloride

Size Price ($) Quantity Availability
1g 33.70
5g 134.00
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Chlorodimethyl(pentafluorophenyl)silane, 96%

MDL
MFCD00000500
EINECS
243-506-9

Chemical Properties

Formula
C8H6ClF5Si
Formula Weight
260.66
Boiling Point
78-81°/10mm
Flash Point
95°(203°F)
Density
1.381
Refractive Index
1.4470
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

It is used as a GC reagent for detection of sterols at low concentration as flophemesyl derivatives, readily detected by electron capture. Chlorodimethyl(pentafluorophenyl)silane is an extremely sensitive derivatizing agent for the analysis of sterols and lower aliphatic alcohols by electron capture gas chromatography.

Notes

Moisture sensitive. Store away from strong bases, water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

Ainsley J. Francis, et al. Flophemesyl derivatives of alcohols, phenols, amines and carboxylic acids and their use in gas chromatography with electron-capture detection.J. Chromatogr. A.,1978,1,(21), 111-117.

E.D. Morgan, et al. Formation of pentafluorophenyldimethylsilylethers and their use in the gas chromatographic analysis of sterols.J. Chromatogr. A.,1975,104(2), 351-358.

GC reagent for detection of sterols at low concentration as flophemesyl derivatives, readily detected by electron capture: J. Chromat., 89, 225 (1974); 104, 351 (1975); 161, 111 (1978); Org. Mass Spectrom., 11, 671 (1978).

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2858407
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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