Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

L00582 Ethyl 3-bromopyruvate, tech. 75%

CAS Number
70-23-5
Synonyms
Bromopyruvic acid ethyl ester
Ethyl 3-bromo-2-oxopropanoate

Stock No. Size Price ($) Quantity Availability
L00582-06 5g 21.70
L00582-14 25g 70.10
L00582-22 100g 222.00
Add to Cart Bulk/Specialty Print Quote View Item

Ethyl 3-bromopyruvate, tech. 75%

MDL
MFCD00000204
EINECS
200-729-6

Chemical Properties

Formula
C5H7BrO3
Formula Weight
195.02
Boiling Point
98-100°/10mm
Flash Point
98°(208°F)
Density
1.555
Refractive Index
1.4690
Storage & Sensitivity
Store under Nitrogen. Keep Cold. Moisture Sensitive.
Solubility
Difficult to mix.

Applications

Ethyl 3-bromopyruvate is employed in a synthesis of thioxothiazolidines from primary amines and carbon disulfide.

Notes

Moisture Sensitive & Hygroscopic. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Dale L. Boger.; Chen, J.H. A Modified Friedlander Condensation for the Synthesis of 3-Hydroxyquinoline-2-carboxylates. J. Org. Chem. 1995, 60, (22), 7369-7371.

Brindaban C. Ranu.; Laksmikanta Adak.; Subhash Banerjee. Ionic liquid promoted interrupted Feist-Benary reaction with high diastereoselectivity. Tetrahedron Letters. 2008, 49, (31), 4613-4617.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1760158
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2918.30
TSCA
Yes

Recommended

  • A10163

    Potassium sodium L-tartrate tetrahydrate, 99%
  • A10228

    4-Bromo-2-fluoroaniline, 98+%
  • A14188

    1,4-Dioxane, 99+%, stab. with ca 5-10ppm BHT
  • A16915

    1-Acetyl-3-thiosemicarbazide, 95%
  • L00720

    Bromopyruvic acid, 97%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware