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1016-58-6 - 4,5-Dimethoxy-2-nitrobenzyl alcohol, 98% - 6-Nitroveratryl alcohol - L00719 - Alfa Aesar

L00719 4,5-Dimethoxy-2-nitrobenzyl alcohol, 98%

CAS Number
1016-58-6
Synonyms
6-Nitroveratryl alcohol

Size Price ($) Quantity Availability
5g 69.73
25g 273.98
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4,5-Dimethoxy-2-nitrobenzyl alcohol, 98%

MDL
MFCD00014701
EINECS
213-806-4

Chemical Properties

Formula
C9H11NO5
Formula Weight
213.19
Melting point
144-148°
Sensitivity
Light Sensitive
Solubility
Soluble in water.

Applications

4,5-Dimethoxy-2-nitrobenzyl alcohol, is used as Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis. It is also used as photochemical protecting groups in organic synthesis. It is also used as a pharmaceutical intermediate.

Notes

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Literature References

S Kantevari.; CV Narasimhaji.; HB Mereyala. Bis (4, 5-dimethoxy-2-nitrophenyl) ethylene glycol: a new and efficient photolabile protecting group for aldehydes and ketones. Tetrahedron. 200561,(24) , 5849-5854.

H Zhao.; ES Sterner.; EB Coughlin.; P Theato. o-Nitrobenzyl alcohol derivatives: opportunities in polymer and materials science. Macromolecules. 201245,(4) , 1723-1736.

Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis: J. Am. Chem. Soc., 92, 6333 (1970); J. Org. Chem., 37, 2281, 2285 (1972).

For reviews of photochemical protecting groups in organic synthesis, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).

Other References

Beilstein
1880093
Harmonized Tariff Code
2909.30
TSCA
No

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