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Selective oxidant which converts benzylic alcohols to aldehydes in high yield: J. Chem. Soc., Chem. Commun., 952 (1978); Tetrahedron Lett., 3331 (1979); J. Org. Chem., 46, 1442 (1981). Oxidizes phenols to o-quinones: J. Chem. Soc., Perkin 1, 1473 (1981): Tetrahedron, 44, 6397 (1988):/n
Reagent for the dehydrogenation of ketones to ɑß-enones and of cyclic enones to dienones: J. Chem. Soc., Perkin 1, 2209 (1980); J. Chem. Soc., Chem. Commun., 1044 (1981). δ-Lactones are also converted to their ɑß-unsaturated derivatives: J. Chem. Soc., Perkin 1, 1919 (1982). Hydrazines can be converted to azo compounds; hydrazine itself gives diimide: J. Org. Chem., 46, 1564 (1981). 3-Substituted indolines give indoles: J. Chem. Soc., Perkin 1, 707 (1990)./n
Monograph: Organoselenium Chemistry, D. Liotta, Ed., Wiley, N.Y. (1987)./n
Hazard Statements: H301-H331-H373
Toxic if swallowed. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P273-P270-P309-P310a-P302+P352a-P501a
Avoid release to the environment. Do not eat, drink or smoke when using this product. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor. IF ON SKIN: Wash with plenty of water. Dispose of contents/container in accordance with local/regional/national/international regulations.