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L00894 Methylamine, 40% w/w aq. soln.

CAS Number
74-89-5
Synonyms

Stock No. Size Price ($) Quantity Availability
L00894-AK 250ml 29.40
L00894-AU 1000ml 40.00
L00894-0F 2500ml 58.80
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Methylamine, 40% w/w aq. soln.

MDL
MFCD00008104
EINECS
200-820-0

Chemical Properties

Formula
CH3NH2
Formula Weight
31.06
Melting point
-38°
Boiling Point
49°
Flash Point
-14°(6°F)
Density
0.899
Refractive Index
1.3710
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water, ethanol, benzene, acetone and ether.

Applications

Methylamine, 40% w/w aq. solution is used as a mobile phase in the perchlorate analysis of milk and yogurt samples by LC-MS/MS. It is also used in the synthesis of 9-fluorenylmethyl N-methylcarbamate and tert-butyl N-methylcarbamate, 7-methylamino-2-(2-quinolyl)tropone, 2,5-meso-pyrrolidines and 2-(4-chlorophenyl)-N-methylacetamide. This compound also serves as a building block for the synthesis of many other commercially available compounds.

Notes

Incompatible with nitromethane, acids, oxidizing agents, hypochlorite, halogenated agents, mercury, copper, copper alloys, zinc, zinc alloys, acid chlorides, acid anhydrides, chloroformates, phosphorus halides aluminum and perchlorates.

Literature References

Song, A.; Lu, G. Catalytic wet oxidation of aqueous methylamine: comparative study on the catalytic performance of platinum-ruthenium, platinum, and ruthenium catalysts supported on titania. Environ. Technol. 2015, 36 (9), 1160-1166.

Earle, M. J.; Noe, M.; Perosa, A.; Seddon, K. R. Improved synthesis of tadalafil using dimethyl carbonate and ionic liquids. RSC Adv. 2014, 4 (3), 1204-1211.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H314-H331

Highly flammable liquid and vapour. Toxic if swallowed. Causes severe skin burns and eye damage. Toxic if inhaled.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P311-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6014
Beilstein
741851
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2921.11
TSCA
Yes
RTECS
PF6300000

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