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4455-77-0 - (Methoxymethyl)diphenylphosphine oxide, 98+% - Diphenyl(methoxymethyl)phosphine oxide - L00912 - Alfa Aesar

L00912 (Methoxymethyl)diphenylphosphine oxide, 98+%

CAS Number
4455-77-0
Synonyms
Diphenyl(methoxymethyl)phosphine oxide

Size Price ($) Quantity Availability
5g 65.30
25g 229.83
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(Methoxymethyl)diphenylphosphine oxide, 98+%

MDL
MFCD00015451
EINECS
224-704-4

Chemical Properties

Formula
C14H15O2P
Formula Weight
246.24
Melting point
113-120°

Literature References

Horner olefination with aldehydes and ketones gives vinyl ethers (and hence higher aldehydes). The method is reported to be superior to the Wittig alternative. The two diastereoisomeric adducts can also be isolated and each converted to a single stereoisomer of the enol ether: J. Chem. Soc., Perkin 1, 3099 (1979):

/n

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H302

Harmful if swallowed.

Precautionary Statements: P264-P270-P301+P312-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
649558
Harmonized Tariff Code
2931.90
TSCA
No
RTECS
SZ0199360

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