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1788-31-4 - Dibenzyl ketoxime, 98+% - 1,3-Diphenylacetone oxime - L00914 - Alfa Aesar

L00914 Dibenzyl ketoxime, 98+%

CAS Number
1788-31-4
Synonyms
1,3-Diphenylacetone oxime

Size Price ($) Quantity Availability
5g 33.10
25g 110.00
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Dibenzyl ketoxime, 98+%

MDL
MFCD00015453
EINECS
217-251-9

Chemical Properties

Formula
C15H15NO
Formula Weight
225.29
Melting point
122-124°
Solubility
Insoluble in water.

Applications

Dibenzyl ketoxime, is used as an intermediate for the preparation of cis-2-benzyl-3-phenylaziridine by reaction with lithium aluminum hydride. It is also used as a pharmaceutical intermediate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Literature References

S Chandrasekhar.; K Gopalaiah. Beckmann rearrangement in the solid state: reaction of oxime hydrochlorides. Tetrahedron Letters. 200142(45) , 8123-8125.

JC Philips.; C Perianayagam. Stereospecific reactions of oximes and oxime derivatives. Tetrahedron Letters. 197516(38) , 3263-3266.

Intermediate for the preparation of cis-2-benzyl-3-phenylaziridine by reaction with lithium aluminum hydride: Org. Synth. Coll., 5, 83 (1973). For a review of this reaction, see: Org. Prep. Proced. Int., 1, 305 (1969):

GHS Hazard and Precautionary Statements

Precautionary Statements: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1965977
Harmonized Tariff Code
2928.00
TSCA
No

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