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2,4,6-Tri-tert-butylnitrobenzene (bulky amine) is used in the synthesis of monomeric iminophosphorane
Ryusei Konaka.; Shigeru Terabe. Spin trapping of short-lived free radicals by use of 2,4,6-tri-tert-butylnitrosobenzene. J. Am. Chem. Soc. 1971 93, (17), 4306-4307.
Guofu Zi.; Laura L. Blosch.; Li Jia.; Richard A. Andersen. Preparation and Reactions of Base-Free Bis(1,2,4-tri-tert-butylcyclopentadienyl)uranium Methylimide, Cp2UNMe, and Related Compounds. Organometallics. 2005, 24, (19), 4602-4612.
Hazard Statements: H302-H312-H331-H315-H319-H335
Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.