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L01554 Trifluoroacetaldehyde ethyl hemiacetal, tech. 80%

CAS Number
433-27-2
Synonyms

Stock No. Size Price ($) Quantity Availability
L01554-06 5g 51.20
L01554-14 25g 187.00
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Trifluoroacetaldehyde ethyl hemiacetal, tech. 80%

MDL
MFCD00000441
EINECS
207-087-6

Chemical Properties

Formula
C4H7F3O2
Formula Weight
144.09
Boiling Point
104-106°
Flash Point
39°(102°F)
Density
1.230
Refractive Index
1.3430
Storage & Sensitivity
Ambient temperatures.

Literature References

Reacts with nucleophilic organosilanes, e.g. allyltrimethylsilane, TMS cyanide or silyl enol ethers, in the presence of a Lewis acid (ZnI2 or AlCl3) to give a series of ɑ-trifluoromethylated alcohols in high yield: Tetrahedron Lett., 33, 1351 (1992).

/n

The synthesis of ɑ-trifluoromethylated alcohols has also been accomplished by In-mediated reaction with allylic bromides in water: Chem. Commun., 1929 (1996).

/n

For a review applications in the synthesis of trifluoromethylated compounds, see: Current Org. Chem., 8, 1659 (2004).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H319

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P264b-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
906797
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2911.00
TSCA
Yes
RTECS
KK9000000

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