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L01710 2,6-Dichlorobenzyl bromide, 97%

CAS Number
20443-98-5
Synonyms
alpha-Bromo-2,6-dichlorotoluene

Stock No. Size Price ($) Quantity Availability
L01710-14 25g 40.30
L01710-22 100g 123.00
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2,6-Dichlorobenzyl bromide, 97%

MDL
MFCD00000577
EINECS
243-827-4

Chemical Properties

Formula
C7H5BrCl2
Formula Weight
239.93
Melting point
54-57°
Flash Point
>110°(230°F)
Storage & Sensitivity
Ambient temperatures.

Literature References

May be used to introduce the 2,6-dichlorobenzyl protecting group for phenols, including the OH group of tyrosine in peptide synthesis. It is readily cleaved with TfOH-TFA in the presence of thioanisole as a cation scavenger: J. Chem. Soc., Chem. Commun., 1063 (1980).

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GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
637351
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
No
RTECS
XS7966000

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