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50-66-8 - 6-(Methylthio)purine, 97% - 6-(Methylmercapto)purine - L01836 - Alfa Aesar

L01836 6-(Methylthio)purine, 97%

CAS Number
50-66-8
Synonyms
6-(Methylmercapto)purine

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6-(Methylthio)purine, 97%

MDL
MFCD00005576
EINECS
200-057-3

Chemical Properties

Formula
C6H6N4S
Formula Weight
166.20
Melting point
220-223°
Solubility
Soluble in water (769 mg/L).

Applications

6-(Methylthio)purine can react with 1-bromo-2-chloro-ethane to produce 6-methylsulfanyl-9-vinyl-9H-purine. This reaction will need reagent NaOH, catalyst (C8H17)4NBr, and the menstruum benzene and H2O.

Notes

Keep container tightly closed. Store away from oxidizing agents.

Literature References

Roland K. Robins. Potential Purine Antagonists. XV. Preparation of Some 6,8-Disubstituted Purines. J. Am. Chem. Soc. 1958, 80, (24), 6671-6679.

B.S. Tay.; R.McC. Lilley.; A.W. Murray.; M.R. Atkinson. Inhibition of phosphoribosyl pyrophosphate amidotransferase from Ehrlich ascites-tumour cells by thiopurine nucleotides. Biochemical Pharmacology. 1969, 18, (4), 936-938.

GHS Hazard and Precautionary Statements

Precautionary Statements: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
7695
Harmonized Tariff Code
2933.59
TSCA
No
RTECS
UO8976000

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