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3481-02-5 - Cyclopropyl phenyl ketone, 97% - Benzoylcyclopropane - L02218 - Alfa Aesar

L02218 Cyclopropyl phenyl ketone, 97%

CAS Number
3481-02-5
Synonyms
Benzoylcyclopropane

Size Price ($) Quantity Availability
25g 62.00
100g 193.00
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Cyclopropyl phenyl ketone, 97%

MDL
MFCD00001294
EINECS
222-458-2

Chemical Properties

Formula
C10H10O
Formula Weight
146.19
Boiling Point
248°
Flash Point
90°(194°F)
Density
1.06
Refractive Index
1.5534
Solubility
Insoluble in water.

Applications

Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

W. J. Close. An Improved Synthesis of Cyclopropyl Phenyl Ketone and Related Substances. J. Am. Chem. Soc. 1957, 79 (6), 1455-1458.

Frank J. Piehl.; Weldon G. Brown. Alkylation of Cyclopropyl Phenyl Ketone. J. Am. Chem. Soc. 1953, 75(20), 5023-5026.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210u-P280a-P370+P378a-P403+P235-P501a

Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1860145
Harmonized Tariff Code
2914.39
TSCA
No

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