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L02218 Cyclopropyl phenyl ketone, 97%

CAS Number
3481-02-5
Synonyms
Benzoylcyclopropane

Stock No. Size Price ($) Quantity Availability
L02218-14 25g 66.50
L02218-22 100g 207.00
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Cyclopropyl phenyl ketone, 97%

MDL
MFCD00001294
EINECS
222-458-2

Chemical Properties

Formula
C10H10O
Formula Weight
146.19
Boiling Point
248°
Flash Point
90°(194°F)
Density
1.06
Refractive Index
1.5534
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

W. J. Close. An Improved Synthesis of Cyclopropyl Phenyl Ketone and Related Substances. J. Am. Chem. Soc. 1957, 79 (6), 1455-1458.

Frank J. Piehl.; Weldon G. Brown. Alkylation of Cyclopropyl Phenyl Ketone. J. Am. Chem. Soc. 1953, 75(20), 5023-5026.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1860145
Harmonized Tariff Code
2914.39
TSCA
No

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