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754-05-2 - Vinyltrimethylsilane, 97% - Trimethylvinylsilane - L02498 - Alfa Aesar

L02498 Vinyltrimethylsilane, 97%

CAS Number
754-05-2
Synonyms
Trimethylvinylsilane

Size Price ($) Quantity Availability
10g 46.14
50g 150.38
250g 587.10
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Vinyltrimethylsilane, 97%

MDL
MFCD00008606
EINECS
212-042-9

Chemical Properties

Formula
C5H12Si
Formula Weight
100.24
Melting point
-132°
Boiling Point
54-56°
Flash Point
-24°(-11°F)
Density
0.690
Refractive Index
1.3910
Solubility
Miscible with tetrahydrofuran, diethyl ether, benzene and dichloromethane.

Applications

Vinyltrimethylsilane is used in semiconductor processing. It is involved in the Preparation of silyl-ethers by Rh(I) catalysis. Further, it is used in the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.

Notes

Store in a cool place. Hygroscopic. Incompatible with strong oxidizing agents, strong acids and strong alkalis (bases).

Literature References

Szudkowska-Fratczak, J.; Marciniec, B.; Hreczycho, G.; Kubicki, M.; Pawluc, P. Ruthenium-Catalyzed Silylation of 1,3-Butadienes with Vinylsilanes. Org. Lett. 2015, 17 (10), 2366-2369.

Szudkowska-Fratczak, J.; Zaranek, M.; Hreczycho, G.; Kubicki, M.; Grabarkiewicz, T.; Pawluc, P. A silicon-assisted synthesis of (E)-beta-haloenamides from N-vinylamides. Appl. Organomet. Chem. 2015, 29 (5), 270-275.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P280g-P243-P305+P351+P338-P403+P233

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store in a well-ventilated place. Keep container tightly closed.

Other References

Beilstein
956572
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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