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L02513 2-(Dimethylamino)pyridine, 97%

CAS Number
5683-33-0
Synonyms

Stock No. Size Price ($) Quantity Availability
L02513-06 5g 23.90
L02513-14 25g 69.20
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2-(Dimethylamino)pyridine, 97%

MDL
MFCD00006261
EINECS
227-147-5

Chemical Properties

Formula
C7H10N2
Formula Weight
122.17
Boiling Point
190-192°
Flash Point
80°(176°F)
Density
1.008
Refractive Index
1.5590
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

2-(Dimethylamino)pyridine in toluene at room temperature in the presence of 1.1 equivalent of methyl trifluoromethanesulfonate forms (2-pyridyl)-trimethylammonium trifluoromethanesulfonate salt. It is used as a model substrate in the preparation of chelate carbene via cyclometalation, H2 loss and reversible α-elimination.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Valérie J. Gandubert and R. Bruce Lennox. Assessment of 4-(Dimethylamino)pyridine as a Capping Agent for Gold Nanoparticles.Langmuir.,2005,21(14), 6532-6539.

G. J. Fox, et al. Bromination of 3-amino- and 3-dimethylamino-pyridine.J. Chem. Soc., Perkin Trans. 1,1973,68-69.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H312-H315-H319-H332-H335

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
110353
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No
RTECS
US9200000

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