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109-05-7 - 2-Methylpiperidine, 98+% - 2-Pipecoline - L02567 - Alfa Aesar

L02567 2-Methylpiperidine, 98+%

CAS Number
109-05-7
Synonyms
2-Pipecoline

Size Price ($) Quantity Availability
100ml 33.27
500ml 117.42
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2-Methylpiperidine, 98+%

MDL
MFCD00005982
EINECS
203-642-1

Chemical Properties

Formula
C6H13N
Formula Weight
99.18
Melting point
-4°
Boiling Point
118-119°
Flash Point
8°(46°F)
Density
0.842
Refractive Index
1.4470
Solubility
It is easily soluble in water.

Applications

2-Methylpiperidine, is used for the oxidation of secondary amines to nitrones by means of H2O2 catalyzed by Sodium tungsten oxide dihydrate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.

Literature References

M Egorova.; Y Zhao.; P Kukula.; R Prins. On the Role of β Hydrogen Atoms in the Hydrodenitrogenation of 2-Methylpyridine and 2-Methylpiperidine. Journal of Catalysis. 2002206(2), 263-271.

LA LaPlanche.; MT Rogers. Configurations in unsymmetrically N, N-disubstituted amides. J. Am. Chem. Soc. 196385(23, 3728-3730.

A useful method for the oxidation of secondary amines to nitrones by means of H2O2 catalyzed by Sodium tungsten oxide dihydrate, 87371 is illustrated for this amine. For method and list of examples, see: Org. Synth. Coll., 9, 632 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P280-P303+P361+P353-P305+P351+P338-P310

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
79804
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
TN1240000

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