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L02589 N-Methyliminodiacetic acid, 99%

CAS Number
4408-64-4
Synonyms

Stock No. Size Price ($) Quantity Availability
L02589-06 5g 46.10
L02589-14 25g 145.00
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N-Methyliminodiacetic acid, 99%

MDL
MFCD00004284
EINECS
224-557-6

Chemical Properties

Formula
C5H9NO4
Formula Weight
147.13
Melting point
ca 220° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water. Slightly soluble in dimethyl sulfoxide.

Applications

N-Methyliminodiacetic acid is used to prepare bis-(1H-benzoimidazol-2-ylmethyl)-methyl-amine by condensation with benzene-1,2-diamine. It is involved in Suzuki cross-coupling with N-methyliminodiacetic acid (MIDA) boronates. It acts as a reagent utilized for protecting boronic acids and as a chelating agent for various metals.

Notes

Incompatible with strong bases.

Literature References

Qi, L.; Zhou, X.; Li, X.; Li, W.; Lv, M.; Guo, M. N-methyliminodiacetic acid as a simple and highly efficient ligand for palladium-catalyzed Suzuki-Miyaura cross-coupling of aryl chlorides. Appl. Organomet. Chem. 2015, 29 (4), 244-246.

Lee, Y. S.; Cheon, C. H. Synthesis of Benzimidazole-Substituted Arylboronic Acids via Aerobic Oxidation of 1, 2-Arylenediamines and Formyl-Substituted Aryl MIDA Boronates using Potassium Iodide as a Catalyst. Adv. Synth. Catal. 2015, 357 (13), 2951-2956.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1765449
Harmonized Tariff Code
2922.49
TSCA
No

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