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1259-35-4 - Tris(pentafluorophenyl)phosphine, 97% - L02748 - Alfa Aesar

L02748 Tris(pentafluorophenyl)phosphine, 97%

CAS Number
1259-35-4
Synonyms

Size Price ($) Quantity Availability
1g 38.38
5g 153.47
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Tris(pentafluorophenyl)phosphine, 97%

MDL
MFCD00079654
EINECS
215-021-2

Chemical Properties

Formula
C18F15P
Formula Weight
532.15
Melting point
115-119°
Solubility
Insoluble in water.

Applications

Tris(pentafluorophenyl)phosphine is an additive for high voltage batteries. It acts as building blocks, coupling reagents, derivatizing reagents.

Notes

Store in a cool, dry, well-ventilated area away from incompatible substances. Handle under inert gas. Incompatible with Strong oxidizing agents.

Literature References

Mengqing Xu; Yanlin Liu; Bin Li; Weishan Li; , Xiaoping Li; Shejun Hu. Tris (pentafluorophenyl) phosphine: An electrolyte additive for high voltage Li-ion batteries.Electrochemistry Communications.2012, 18 123-126.

A. Karipides and C. M. Cosio. Structure of tris(pentafluorophenyl)phosphine.Acta Cryst.1989, 45 1743-1745 .

Standard for mass spectrometry.

In a study of Pd-catalyzed coupling reactions in supercritical CO2, this ligand was among the best tried for the Heck reaction, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
773243
Harmonized Tariff Code
2931.90
TSCA
No

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