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L02753 2-Acetylcyclohexanone, 98%

CAS Number
874-23-7
Synonyms

Stock No. Size Price ($) Quantity Availability
L02753-06 5g 29.50
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2-Acetylcyclohexanone, 98%

MDL
MFCD00001633
EINECS
212-858-5

Chemical Properties

Formula
C8H12O2
Formula Weight
140.18
Boiling Point
111-112°/18mm
Flash Point
79°(174°F)
Density
1.063
Refractive Index
1.5110
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible in water.

Applications

2-Acetylcyclohexanone is useful for synthesis of anilinoethanolamines, 1-(pyridyl)ethanol derivatives that can reduce keto-esters and ketones. It is also used in the synthesis of phenothiazine derivatives that can inhibit prote in farnesyltransferase molecules and some that show anti-proliferative activity.

Notes

Incompatible with Strong oxidizing agents, Strong bases. Air-sensitive.

Literature References

Emilia Iglesias. Tautomerization of 2-Acetylcyclohexanone. 1. Characterization of Keto-Enol/Enolate Equilibria and Reaction Rates in Water.J. Org. Chem.2003, 68 (7), 2680-2688.

Fillmore Freeman; Donald K. Fraquhar; Robert L. Walker. Reaction of 2-acetylcyclohexanone with malononitrile and cyanoacetamide.J. Org. Chem.1968, 33 (9), 3648-3650.

For conversion to the ɑß-unsaturated diketone by selenoxide elimination, see Phenyl­selenenyl­ chloride, A12751.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1858621
Harmonized Tariff Code
2914.29
TSCA
Yes

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