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2-Iodo-2-methylpropane is used as a chemical reagent in organic synthesis. Further, it serves as a pharmaceutical intermediate.
With DMSO, generates iodomethylsulfonium iodide, a reagent which is more reactive than that derived from tert-Butyl bromide, A13727 for the cleavage of ethylene thioacetals.
Fujii, S.; Nakano, M.; Yamaoka, Y.; Takasu, K.; Yamada, K. I.; Tomioka, K. Contiguous radical pivaloyloxymethylation-directed C(sp3)-H iodination of N-tosyl cycloalkanecarbaldimine. Tetrahedron Lett. 2015, 56 (23), 3086-3089.
Ma, G.; Fujita, T.; Sibi, M. P. Lewis acid mediated diastereoselective intermolecular radical addition/trapping with pyrazolidinone acrylimides. Tetrahedron Lett. 2015, 56 (23), 3571-3574.
Hazard Statements: H225-H315-H319-H335
Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P260-P201-P280h-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.