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558-17-8 - 2-Iodo-2-methylpropane, 95%, stab. with copper powder - tert-Butyl iodide - L02786 - Alfa Aesar

L02786 2-Iodo-2-methylpropane, 95%, stab. with copper powder

CAS Number
558-17-8
Synonyms
tert-Butyl iodide

Size Price ($) Quantity Availability
25g 62.01
100g 171.00
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2-Iodo-2-methylpropane, 95%, stab. with copper powder

MDL
MFCD00001068
EINECS
209-190-1

Chemical Properties

Formula
C4H9I
Formula Weight
184.02
Melting point
-38°
Boiling Point
99-100°
Flash Point
7°(44°F)
Density
1.547
Refractive Index
1.4910
Sensitivity
Light Sensitive
Solubility
Miscible with ethanol and ether.

Applications

2-Iodo-2-methylpropane is used as a chemical reagent in organic synthesis. Further, it serves as a pharmaceutical intermediate.

Notes

Light sensitive. Incompatible with strong oxidizing agents and strong bases.

Literature References

With DMSO, generates iodomethylsulfonium iodide, a reagent which is more reactive than that derived from tert-Butyl­ bromide, A13727 for the cleavage of ethylene thioacetals.

Fujii, S.; Nakano, M.; Yamaoka, Y.; Takasu, K.; Yamada, K. I.; Tomioka, K. Contiguous radical pivaloyloxymethylation-directed C(sp3)-H iodination of N-tosyl cycloalkanecarbaldimine. Tetrahedron Lett. 2015, 56 (23), 3086-3089.

Ma, G.; Fujita, T.; Sibi, M. P. Lewis acid mediated diastereoselective intermolecular radical addition/trapping with pyrazolidinone acrylimides. Tetrahedron Lett. 2015, 56 (23), 3571-3574.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P260-P280h-P243-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
505950
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
TZ4251000

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