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100-79-8 - Solketal, 97% - (+/-)-2,2-Dimethyl-1,3-dioxolane-4-methanol - (+/-)-2,3-O-Isopropylideneglycerol - L02814 - Alfa Aesar

L02814 Solketal, 97%

CAS Number
100-79-8
Synonyms
(+/-)-2,2-Dimethyl-1,3-dioxolane-4-methanol
(+/-)-2,3-O-Isopropylideneglycerol

Size Price ($) Quantity Availability
100g 26.28
500g 59.84
2500g 191.58
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Solketal, 97%

MDL
MFCD00063238
EINECS
202-888-7

Chemical Properties

Formula
C6H12O3
Formula Weight
132.16
Melting point
-27°
Boiling Point
188-190°
Flash Point
80°(176°F)
Density
1.064
Refractive Index
1.4340
Solubility
Soluble in water (fully), alcohol, acetals, esters, and ethers.

Applications

Solketal is useful for synthesis of mono-, di- and triglycerides. It is used as the starting reagent for synthesis of tulipaline derivatives. It acts as a fuel additive in gasoline. It is an inhibitor of Methyl ethyl ketone .

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible materials are acids, Strong oxidizing agents.

Literature References

Claudio J. A. Mota; Carolina X. A. da Silva;Nilton Rosenbach; Jair Costa and Flávia da Silva. Glycerin Derivatives as Fuel Additives: The Addition of Glycerol/Acetone Ketal (Solketal) in Gasolines.Energy Fuels.2010, 24 (4), 2733-2736.

Jan-Willem Hofman; Femke van Zeeland; Selcan Turker; Herre Talsma; Saskia A. G. Lambrechts; Dmitri V. Sakharov; Wim E. Hennink and Cornelus F. van Nostrum. Peripheral and Axial Substitution of Phthalocyanines with Solketal Groups:? Synthesis and In Vitro Evaluation for Photodynamic Therapy.J. Med. Chem.2007, 50 (7), 1485-1494.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5213
Beilstein
104465
Harmonized Tariff Code
2932.99
TSCA
Yes
RTECS
JI0400000

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