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768-32-1 - Phenyltrimethylsilane, 99% - Trimethylphenylsilane - L02876 - Alfa Aesar

L02876 Phenyltrimethylsilane, 99%

CAS Number
768-32-1
Synonyms
Trimethylphenylsilane

Size Price ($) Quantity Availability
5g 22.70
25g 73.90
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Phenyltrimethylsilane, 99%

MDL
MFCD00008271
EINECS
212-192-5

Chemical Properties

Formula
C9H14Si
Formula Weight
150.30
Boiling Point
169-170°
Flash Point
40°(104°F)
Density
0.871
Refractive Index
1.4900
Solubility
Not miscible or difficult to mix with water.

Applications

It is employed as intermediate for pharmaceutical and organic synthesis.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Ralph J. Fessenden; Ray A. Hartman. Metabolic fate of phenyltrimethylsilane and phenyldimethylsilane. J. Med. Chem., 1970,13(1), 52-54.

J. A. Bedford; J. R. Bolton; A. Carrington; and R. H. Prince. The electron spin resonance spectra of the phenyltrimethylsilane and -germane anions: π-bonding between silicon and germanium and the aromatic ring. Trans. Faraday Soc.., 1963,5953-58.

Reagent, in combination with iodine, for cleavage of esters and ethers, cf Iodotrimethyl­silane, A12902. Reported to be superior to TMS iodide for the cleavage of aryl ethers: Synthesis, 417 (1977).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P261-P280g-P305+P351+P338

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1855012
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
Yes

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