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L02876 Phenyltrimethylsilane, 99%

CAS Number
768-32-1
Synonyms
Trimethylphenylsilane

Stock No. Size Price ($) Quantity Availability
L02876-06 5g 23.60
L02876-14 25g 76.80
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Phenyltrimethylsilane, 99%

MDL
MFCD00008271
EINECS
212-192-5

Chemical Properties

Formula
C9H14Si
Formula Weight
150.30
Boiling Point
169-170°
Flash Point
40°(104°F)
Density
0.871
Refractive Index
1.4900
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix with water.

Applications

It is employed as intermediate for pharmaceutical and organic synthesis.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Ralph J. Fessenden; Ray A. Hartman. Metabolic fate of phenyltrimethylsilane and phenyldimethylsilane. J. Med. Chem., 1970,13(1), 52-54.

J. A. Bedford; J. R. Bolton; A. Carrington; and R. H. Prince. The electron spin resonance spectra of the phenyltrimethylsilane and -germane anions: π-bonding between silicon and germanium and the aromatic ring. Trans. Faraday Soc.., 1963,5953-58.

Reagent, in combination with iodine, for cleavage of esters and ethers, cf Iodotrimethyl­silane, A12902. Reported to be superior to TMS iodide for the cleavage of aryl ethers: Synthesis, 417 (1977).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1855012
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
Yes

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