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L03063 Tetrahydrothiopyran, 98%

CAS Number
1613-51-0
Synonyms
Pentamethylene sulfide
Thiane

Stock No. Size Price ($) Quantity Availability
L03063-03 1g 22.90
L03063-06 5g 54.30
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Tetrahydrothiopyran, 98%

MDL
MFCD00006662
EINECS
216-561-1

Chemical Properties

Formula
C5H10S
Formula Weight
102.20
Boiling Point
140-142°
Flash Point
21°(69°F)
Density
0.988
Refractive Index
1.5060
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

It is a useful 5 c synthon for the synthesis of 3-cyclopentenones. It is a organic sulfide, that has shown to have antioxidant activity.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep away from ignition sources. Protect against electrostatic charges.

Literature References

Néstor M. Carballeira, et al. Thietane, tetrahydrothiophene and tetrahydrothiopyran formation in reaction of methylene-interrupted dienoates with dimethyl disulfide.Tetrahedron Lett.,1994,35(31), 5575-5578.

Junji Fujita, et al. Synthesis of thiosaccharides employing the Pummerer rearrangement of tetrahydrothiopyran oxides.Tetrahedron.,2004,60(32), 6829-6851.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
102437
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2934.99
TSCA
No

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