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L03140 Triphenylcarbenium hexafluorophosphate, 98%

CAS Number
437-17-2
Synonyms
Tritylium hexafluorophosphate
Trityl hexafluorophosphate

Stock No. Size Price ($) Quantity Availability
L03140-09 10g 62.70
L03140-18 50g 266.00
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Triphenylcarbenium hexafluorophosphate, 98%

MDL
MFCD00013121
EINECS
207-112-0

Chemical Properties

Formula
C19H15F6P
Formula Weight
388.29
Melting point
ca 160° dec.
Storage & Sensitivity
Store at -20°C. Moisture Sensitive. Store under Nitrogen.
Solubility
Soluble in water. (27 g/L) at 25°C.

Applications

Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.

Notes

Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.

Literature References

Jan Voigt; Thomas Braun. Si-H and Si-Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes.Dalton Transactions.2011, 40 (47), 12699-12704.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4344297
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2942.00
TSCA
Yes

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