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924-41-4 - 1,5-Hexadien-3-ol, 95% - Allyl vinyl carbinol - L03182 - Alfa Aesar

L03182 1,5-Hexadien-3-ol, 95%

CAS Number
924-41-4
Synonyms
Allyl vinyl carbinol

Size Price ($) Quantity Availability
2g 32.60
10g 89.00
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1,5-Hexadien-3-ol, 95%

MDL
MFCD00008662
EINECS
213-102-7

Chemical Properties

Formula
C6H10O
Formula Weight
98.15
Boiling Point
133-134°
Flash Point
29°(84°F)
Density
0.877
Refractive Index
1.4480
Solubility
Sparingly Soluble.

Applications

1,5-Hexadien-3-ol is used in the synthesis of (+)-obtusenyne. It is used as intermediates. It undergoes Sharpless kinetic resolution and ring-closing metathesis to yield nine membered oxocene.

Notes

Keep away from heat. Incompatible with Oxidizing agents.

Literature References

Michael T Crimmins; Mark T Powell. Enantioselective total synthesis of (+)-obtusenyne.Journal of the American Chemical Society.2003, 125 (25), 7592-7595.

Thomas W. Gibson; William F. Erman. Photochemistry of substituted 1,5-hexadien-3-ones.J. Org. Chem.1972, 37 (8), 1148-1154.

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1719962
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.29
TSCA
No

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