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Trimethylsilyl isothiocyanate is used as derivatizing reagent during the synthesis of amino acid thiohydantoins. It participates in ring opening reaction of N-substituted aziridines and cyclohexene oxide.
B Mo; J Li; S Liang. A method for preparation of amino acid thiohydantoins from free amino acids activated by acetyl chloride for development of protein C-terminal sequencing.Analytical Biochemistry.1997, 247 (2), 207-211.
Xiaobing Yang; Shaohua Huang; Zhenshan Jia; Zuo Xiao; Zhongping Jiang; Qianyan Zhang, Liangbing Gan; Bo Zhen;, Gu Yuan; Shiwei Zhang. Reactivity of fullerene epoxide: preparation of fullerene-fused thiirane, tetrahydrothiazolidin-2-one, and 1,3-dioxolane.Journal of Organic Chemistry.2008, 73 (7), 2518-2526.
Protected form of "HNCS".
Hazard Statements: H226-H301-H331-H315-H319-H335
Flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P280-P305+P351+P338-P309-P310a
Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor