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(Methylsulfonyl)acetonitrile was used in the synthesis of substituted δ-pyrone ring analogues, 4,9-dihydropyrrolo[2,1-b]quinazolines containing electron withdrawing groups at the 3-position.
Ronald B. Gammill; Sharon A. Nash; Larry T. Bell; William Watt. A novel entry to substituted chromones and furochromones through cyclopropane intermediates. Tetrahedron Letters. 1992, 33, (8), 997-1000.
Nisaraporn Suthiwangcharoen; Steven M. Pochini; Daniel P. Sweat and Chad E. An intramolecular N-arylation approach to 3-functionalized 4,9-dihydropyrrolo[2,1-b]quinazolines. Journal of Heterocyclic Chemistry. 2011, 48, (3), 706-709.
Hazard Statements: H302-H312-H332
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.
Precautionary Statements: P280h-P302+P352a
Wear protective gloves/clothing. IF ON SKIN: Wash with plenty of water.