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L03280 Methylsulfonylacetonitrile, 98+%

CAS Number
2274-42-2
Synonyms
Methanesulfonylacetonitrile

Stock No. Size Price ($) Quantity Availability
L03280-09 10g 110.00
L03280-18 50g 429.00
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Methylsulfonylacetonitrile, 98+%

MDL
MFCD00014743
EINECS
218-888-5

Chemical Properties

Formula
C3H5NO2S
Formula Weight
119.14
Melting point
82-86°
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

(Methylsulfonyl)acetonitrile was used in the synthesis of substituted δ-pyrone ring analogues, 4,9-dihydropyrrolo[2,1-b]quinazolines containing electron withdrawing groups at the 3-position.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Ronald B. Gammill; Sharon A. Nash; Larry T. Bell; William Watt. A novel entry to substituted chromones and furochromones through cyclopropane intermediates. Tetrahedron Letters. 1992, 33, (8), 997-1000.

Nisaraporn Suthiwangcharoen; Steven M. Pochini; Daniel P. Sweat and Chad E. An intramolecular N-arylation approach to 3-functionalized 4,9-dihydropyrrolo[2,1-b]quinazolines. Journal of Heterocyclic Chemistry. 2011, 48, (3), 706-709.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H315-H319-H331-H335

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. Toxic if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P311-P312-P330-P332+P313-P337+P313-P361-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
969929
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
No

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