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Crotonaldehyde is used as intermediates. It is an excellent prochiral dienophile.
M.Albert Vannice; B. Sen. Metal-support effects on the intramolecular selectivity of crotonaldehyde hydrogenation over platinum.Journal of Catalysis.1989, 115 65-78.
Noel S. Bayliss; Eion G. McRae. Solvent Effects in the Spectra of Acetone, Crotonaldehyde, Nitromethane and Nitrobenzene.J. Phys. Chem.1989, 58 (11), 1006-1011.
Hazard Statements: H225-H301-H310+H330-H315-H318-H335-H341-H372
Highly flammable liquid and vapour. Toxic if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Suspected of causing genetic defects. Causes damage to organs through prolonged or repeated exposure.
Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P262-P264b-P270-P271-P281-P284-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P332+P313-P363-P370+P378
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation occurs: Wash contaminated clothing before reuse. In case of fire: Use for extinction: