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L03398 1-Methylpiperidine, 99%

CAS Number
626-67-5
Synonyms

Stock No. Size Price ($) Quantity Availability
L03398-09 10g 23.80
L03398-22 100g 34.60
L03398-36 500g 126.00
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1-Methylpiperidine, 99%

MDL
MFCD00006491
EINECS
210-959-9

Chemical Properties

Formula
C6H13N
Formula Weight
99.18
Melting point
-50°
Boiling Point
105-107°
Flash Point
3°(37°F)
Density
0.816
Refractive Index
1.4378
Storage & Sensitivity
Ambient temperatures.
Solubility
Fully miscible in water.

Applications

1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with.acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Carbon dioxide.

Literature References

Amina A. Fakhroo; Hassan S. Bazzi; Adel Mostafa; Lamis Shahada. Synthesis, spectroscopic and thermal structural investigations of the charge-transfer complexes formed in the reaction of 1-methylpiperidine with ?- and π-acceptors.Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. Chem.2010, 75 134-141.

G. Smith and G. A. Swan. The chemical effects of γ-radiation on organic systems. Part IV. The action of radiation on diethylamine, trimethylamine, benzylamine, phenethylamine, 1-methylpiperidine, N-methyldiethylamine, and t-butylamine.J. Chem. Soc. Chem.1962, 168 886-904.

Use of this base in the mixed anhydride method of peptide coupling reduces cleavage of the mixed anhydride at the "wrong" site: J. Org. Chem., 48, 2939 (1983). See Appendix 6.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H312-H314-H332-H335

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1073
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
TN1225000

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