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5000-46-4 - Methylsulfonylacetone, 98+% - Methanesulfonylacetone - 1-Methylsulfonyl-2-propanone - L03421 - Alfa Aesar

L03421 Methylsulfonylacetone, 98+%

CAS Number
5000-46-4
Synonyms
Methanesulfonylacetone
1-Methylsulfonyl-2-propanone

Size Price ($) Quantity Availability
2g 28.90
10g 83.50
50g 300.00
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Methylsulfonylacetone, 98+%

MDL
MFCD00014745
EINECS
225-665-6

Chemical Properties

Formula
C4H8O3S
Formula Weight
136.18
Melting point
47-52°
Solubility
Insoluble in water.

Applications

Methylsulfonylacetone is used as reactant for Stereoselective preparation of chiral cyclic ketones. It is used in the Preparation of poly-substituted pyridines. It aids for Gold-catalyzed Friedlander cyclocondensation reaction. It is used as reactant in Radical homoallylation reactions, multicomponent cyclocondensation with aldehydes and aminoazoles.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible materials are Strong oxidizing agents

Literature References

Smaranda C Marinescu; Toyoki Nishimata; Justin T Mohr; Brian M Stoltz. Homogeneous pd-catalyzed enantioselective decarboxylative protonation.Organic Letters.2008, 10 (6), 1039-1042.

Other References

Beilstein
1754113
Harmonized Tariff Code
2930.90
TSCA
No

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