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995-45-9 - Chlorotri-n-butylsilane, 97% - Tri-n-butylchlorosilane - Tri-n-butylsilyl chloride - L03477 - Alfa Aesar

L03477 Chlorotri-n-butylsilane, 97%

CAS Number
995-45-9
Synonyms
Tri-n-butylchlorosilane
Tri-n-butylsilyl chloride

Size Price ($) Quantity Availability
5g 47.80
25g 188.00
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Chlorotri-n-butylsilane, 97%

MDL
MFCD00000509
EINECS
213-627-1

Chemical Properties

Formula
C12H27ClSi
Formula Weight
234.89
Boiling Point
93-94°/4mm
Flash Point
104°(219°F)
Density
0.883
Refractive Index
1.4460
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

Chlorotri-n-butylsilane is as silylating agent. It can react with bromo-trifluoro-methane, to product tributyl-trifluoromethyl-silane.

Notes

Moisture sensitive. Store away from strong oxidizing agents, water/ moisture.

Literature References

Henry Gilman; David H. Miles; Leonard O. Moore; Clare W. Gerow. Some Organosilicon Compounds Containing Long-Chained n-Alkyl Groups. J. Org. Chem. 1959, 24, (2), 219-224.

Samia Zrig; Guy Koeckelberghs; Thierry Verbiest; Bruno Andrioletti; Eric Rose; André Persoons; Inge Asselberghs and Koen Clays. Λ-Type Regioregular Oligothiophenes:? Synthesis and Second-Order NLO Properties. J. Org. Chem. 2007, 72, (15), 5855-5858.

Silylating agent.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1742537
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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