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352-93-2 - Diethyl sulfide, 96% - Ethyl sulfide - L03493 - Alfa Aesar

L03493 Diethyl sulfide, 96%

CAS Number
352-93-2
Synonyms
Ethyl sulfide

Size Price ($) Quantity Availability
10g 29.56
100g 101.60
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Diethyl sulfide, 96%

MDL
MFCD00009270
EINECS
206-526-9

Chemical Properties

Formula
CH3CH2SCH2CH3
Formula Weight
90.19
Melting point
-104°
Boiling Point
90-92°
Flash Point
-10°(14°F)
Density
0.835
Refractive Index
1.4420
Solubility
Miscible with alcohol, ethanol and ether. Slightly miscible with carbon tetrachloride. Immiscible with water.

Applications

Diethyl sulfide is used as a solvent for anhydrous mineral salts and in plating baths for coating metals with gold or silver. It is used as a flavoring agent. It is also used in the addition reaction with platinum dichloride to prepare platinum ethynyl dimers and polymers with pendant ferrocenyl group. Further, it is used in the preparation of triethylsulfoniuim ethylsulfate by reaction with sulfuric acid diethyl ester. In addition to this, it is used in the quantification procedure of volatile sulfur compounds by solid-phase microextraction.

Notes

Incompatible with strong oxidizing agents.

Literature References

Besov, A. S.; Vorontsov, A. V. Adsorption and photocatalytic oxidation of acetone and diethyl sulfide on FeOOH aerosol. Colloid J. 2015, 77 (1), 11-15.

Oksdath-Mansilla, G.; Peñéñory, A. B.; Barnes, I.; Wiesen, P.; Teruel, M. A. Product distribution study of the Cl-atom initiated oxidation of ethyl methyl sulfide and diethyl sulfide. Atmos. Environ. 2014, 85, 41-47.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3854
Beilstein
1696909
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2930.90
TSCA
Yes
RTECS
LC7200000

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