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L03602 Chlorodiphenylsilane, tech. 90%

CAS Number
1631-83-0
Synonyms
Diphenylchlorosilane

Stock No. Size Price ($) Quantity Availability
L03602-06 5g 70.30
L03602-14 25g 248.00
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Chlorodiphenylsilane, tech. 90%

MDL
MFCD00045144
EINECS
216-634-8

Chemical Properties

Formula
C12H11ClSi
Formula Weight
218.76
Boiling Point
280°
Flash Point
105°(221°F)
Density
1.123
Refractive Index
1.5790
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Reacts with water.

Applications

Chlorodiphenylsilane is used in Medicine field, electronics industry, polymer materials. It is used in reduction of alcohols.

Notes

Moisture Sensitive. Store away from bases, water. Incompatible with oxidizing agents and water.

Literature References

Makoto Yasuda; Yoshiyuki Onishi; Masako Ueba; Takashi Miyai and Akio Baba. Direct Reduction of Alcohols:? Highly Chemoselective Reducing System for Secondary or Tertiary Alcohols Using Chlorodiphenylsilane with a Catalytic Amount of Indium Trichloride.J. Org. Chem.2001, 66 (23), 7741-7744.

V. Bazant and M. Cerny. Synthesis of p-bis-silylarylene compounds by the Grignard reaction of p-dichlorobenzene with dialkoxy-, dichloro-, alkoxychloro- and chlorodiphenylsilanes.Collect. Czech. Chem. Commun.1974, 39 1728-1734.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2937164
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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