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L03634 Iodoacetonitrile, 97%

CAS Number
624-75-9
Synonyms

Stock No. Size Price ($) Quantity Availability
L03634-09 10g 43.00
L03634-18 50g 132.00
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Iodoacetonitrile, 97%

MDL
MFCD00001886
EINECS
210-860-0

Chemical Properties

Formula
C2H2IN
Formula Weight
166.95
Boiling Point
70-72°/10mm
Flash Point
86°(186°F)
Density
2.306
Refractive Index
1.5740
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Soluble in benzene, alcohol, acetone, ether. Slightly soluble in water. Insoluble in hexane.

Applications

Iodoacetonitrile is used for alkylation of nucleophiles. It undergoes Reformatsky and Wittig-type reactions with aldehydes.

Notes

Light Sensitive. Store at 4°C. Incompatible with reducing agents, light and bases. Store away from strong bases.

Literature References

Paul G. Wenthold. Determination of the proton affinities of bromo- and iodoacetonitrile using the kinetic method with full entropy analysis.Journal of the American Society for Mass Spectrometry.2000, 11 601-605.

W. C. Kupferschmidt; R. B. Jordan. Reactions of chromium(II) with chloro- and iodoacetonitrile and their pentaamminecobalt(III) complexes.J. Am. Chem. Soc..1984, 106 (4), 991-995.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H301-H311-H314-H331-H335

Combustible liquid. Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1734628
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
AM0740000

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