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624-75-9 - Iodoacetonitrile, 97% - L03634 - Alfa Aesar

L03634 Iodoacetonitrile, 97%

CAS Number
624-75-9
Synonyms

Size Price ($) Quantity Availability
10g 41.00
50g 126.00
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Iodoacetonitrile, 97%

MDL
MFCD00001886
EINECS
210-860-0

Chemical Properties

Formula
C2H2IN
Formula Weight
166.95
Boiling Point
70-72°/10mm
Flash Point
86°(186°F)
Density
2.306
Refractive Index
1.5740
Sensitivity
Light Sensitive
Solubility
Soluble in benzene, alcohol, acetone, ether. Slightly soluble in water. Insoluble in hexane.

Applications

Iodoacetonitrile is used for alkylation of nucleophiles. It undergoes Reformatsky and Wittig-type reactions with aldehydes.

Notes

Light Sensitive. Store at 4°C. Incompatible with reducing agents, light and bases. Store away from strong bases.

Literature References

Paul G. Wenthold. Determination of the proton affinities of bromo- and iodoacetonitrile using the kinetic method with full entropy analysis.Journal of the American Society for Mass Spectrometry.2000, 11 601-605.

W. C. Kupferschmidt; R. B. Jordan. Reactions of chromium(II) with chloro- and iodoacetonitrile and their pentaamminecobalt(III) complexes.J. Am. Chem. Soc..1984, 106 (4), 991-995.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H302-H312-H332-H227

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Combustible liquid.

Precautionary Statements: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1734628
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
AM0740000

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