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L03703 Allyltrichlorosilane, 95%

CAS Number
107-37-9
Synonyms

Stock No. Size Price ($) Quantity Availability
L03703-06 5g 37.80
L03703-14 25g 131.00
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Allyltrichlorosilane, 95%

MDL
MFCD00000486
EINECS
203-485-9

Chemical Properties

Formula
C3H5Cl3Si
Formula Weight
175.52
Boiling Point
117-118°
Flash Point
18°(64°F)
Density
1.211
Refractive Index
1.4490
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in THF, toluene, benzene. Reacts with water.

Applications

Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.

Notes

Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and moisture. Incompatible with water.

Literature References

Sh? Kobayashi; Chikako Ogawa; Hideyuki Konishi and Masaharu Sugiura. Chiral Sulfoxides as Neutral Coordinate-Organocatalysts in Asymmetric Allylation of N-Acylhydrazones Using Allyltrichlorosilanes.J. Am. Chem. Soc.2003, 125 (22), 6610-6611.

Ryoji Hirabayashi; Chikako Ogawa; Masaharu Sugiura and Sh? Kobayashi. Highly Stereoselective Synthesis of Homoallylic Amines Based on Addition of Allyltrichlorosilanes to Benzoylhydrazones.J. Am. Chem. Soc.2001, 123 (39), 9493-9499.

Allyltrichlorosilanes react with aldehydes in DMF without a catalyst to give high yields of the corresponding homoallylic alcohols, for example allyltrichlorosilane with benzaldehyde gives 1-phenyl-3-buten-1-ol and with cinnamaldehyde gives 1-phenyl-1,5-hexadien-3-ol, both in high yield: Tetrahedron Lett., 34, 3453 (1993); J. Org. Chem., 59, 6620 (1994).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1743449
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
VV1530000

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