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123-39-7 - N-Methylformamide, 99% - N-Formylmethylamine - L03908 - Alfa Aesar

L03908 N-Methylformamide, 99%

CAS Number
123-39-7
Synonyms
N-Formylmethylamine

Size Price ($) Quantity Availability
50g 17.91
250g 33.89
1000g 75.40
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N-Methylformamide, 99%

MDL
MFCD00003280
EINECS
204-624-6

Chemical Properties

Formula
C2H5NO
Formula Weight
59.07
Melting point
-4°
Boiling Point
181-185°
Flash Point
98°(208°F)
Density
1.018
Refractive Index
1.4320
Solubility
Miscible with water, acetone and ethanol. Immiscible with ether.

Applications

N-Methylformamide is used to prepare methyl isocyanate. It is used as an extraction solvent for aromatic hydrocarbons and acts as a ligand in coordination chemistry. It is employed as a solvent in oil refineries and in aluminum electrolytic capacitors. Further, it is used as a reagent in organic synthesis. In addition to this, it is used as an investigational anticancer drug and an intermediate in the production of some pharmaceutical compounds.

Notes

Incompatible with strong oxidizing agents, acids, bases and acid chlorides.

Literature References

Reagent for replacement of an activated chlorine in an aromatic or heteroaromatic ring by the methylamino group: Synthesis, 39 (1980).

Precursor of methyl isocyanide (highly toxic!), by dehydration with tosyl chloride in pyridine: Org. Synth. Coll., 5, 772 (1973).

Emets, V. V.; Damaskin, B. B. Two-dimensional pressure of chemisorbed dimethylformamide and N-methylformamide molecules at Ga-, (In-Ga)-, and (Tl-Ga)-electrodes. Russ. J. Electrochem. 2015, 51 (8), 789-795.

Bunkan, A. J. C.; Hetzler, J.; Mikoviny, T.; Wisthaler, A.; Nielsen, C. J.; Olzmann, M. The reactions of N-methylformamide and N,N-dimethylformamide with OH and their photo-oxidation under atmospheric conditions: experimental and theoretical studies. Phys. Chem. Chem. Phys. 2015, 17, 7046-7059.

GHS Hazard and Precautionary Statements

Hazard Statements: H360-H312

May damage fertility or the unborn child. Harmful in contact with skin.

Precautionary Statements: P201-P280-P281-P312-P363-P308+P313-P322-P302+P352-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Specific measures (see label). IF ON SKIN: Wash with plenty of soap and water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6076
Beilstein
1098352
Harmonized Tariff Code
2924.19
TSCA
Yes
RTECS
LQ3000000

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