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928-51-8 - 4-Chloro-1-butanol, tech. 85% - Tetramethylene chlorohydrin - L04042 - Alfa Aesar

L04042 4-Chloro-1-butanol, tech. 85%

CAS Number
928-51-8
Synonyms
Tetramethylene chlorohydrin

Size Price ($) Quantity Availability
50g 50.90
250g 176.00
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4-Chloro-1-butanol, tech. 85%

MDL
MFCD00002967
EINECS
213-175-5

Chemical Properties

Formula
C4H9ClO
Formula Weight
108.57
Boiling Point
50-52°/1mm
Flash Point
36°(97°F)
Density
1.089
Refractive Index
1.4570
Solubility
Soluble in methanol, chloroform, and dimethyl sufoxide.

Applications

4-Chloro-1-butanol is employed as an internal standard in the analysis of genotoxic impurities in active pharmaceutical ingredients by GC-MS technique.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Otto Bastiansen.; Liv Fernholt.; Kenneth Hedberg.; Ragnhild Seip. Structure and conformations of 4-chloro-1-butanol: electron-diffraction evidence for internal hydrogen bonding. J. Am. Chem. Soc. 1985, 107 (26), 7836-7841.

Koki Harigaya.; Hiroyuki Yamada.; Koji Yaku.; Hiroyuki Nishi.; Jun Haginaka. Development and validation of a sensitive GC-MS method for the determination of alkylating agent, 4-chloro-1-butanol, in active pharmaceutical ingredients. Journal of Molecular Biology. 1997, 113 (1), 237-251.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H290-H302-H333-H314-H318-H351-H335

Flammable liquid and vapour. May be corrosive to metals. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1731408
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.59
TSCA
Yes
RTECS
EL1325000

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