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928-51-8 - 4-Chloro-1-butanol, tech. 85% - Tetramethylene chlorohydrin - L04042 - Alfa Aesar

L04042 4-Chloro-1-butanol, tech. 85%

CAS Number
928-51-8
Synonyms
Tetramethylene chlorohydrin

Size Price ($) Quantity Availability
50g 50.88
250g 178.19
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4-Chloro-1-butanol, tech. 85%

MDL
MFCD00002967
EINECS
213-175-5

Chemical Properties

Formula
C4H9ClO
Formula Weight
108.57
Boiling Point
50-52°/1mm
Flash Point
66°(151°F)
Density
1.089
Refractive Index
1.4570
Solubility
Soluble in methanol, chloroform, and dimethyl sufoxide.

Applications

4-Chloro-1-butanol is employed as an internal standard in the analysis of genotoxic impurities in active pharmaceutical ingredients by GC-MS technique.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Otto Bastiansen.; Liv Fernholt.; Kenneth Hedberg.; Ragnhild Seip. Structure and conformations of 4-chloro-1-butanol: electron-diffraction evidence for internal hydrogen bonding. J. Am. Chem. Soc. 1985, 107 (26), 7836-7841.

Koki Harigaya.; Hiroyuki Yamada.; Koji Yaku.; Hiroyuki Nishi.; Jun Haginaka. Development and validation of a sensitive GC-MS method for the determination of alkylating agent, 4-chloro-1-butanol, in active pharmaceutical ingredients. Journal of Molecular Biology. 1997, 113 (1), 237-251.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335-H227

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1731408
Harmonized Tariff Code
2905.59
TSCA
Yes
RTECS
EL1325000

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