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2550-04-1 - Allyltriethoxysilane, 97% - L04297 - Alfa Aesar

L04297 Allyltriethoxysilane, 97%

CAS Number
2550-04-1
Synonyms

Size Price ($) Quantity Availability
5g 42.10
25g 137.00
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Allyltriethoxysilane, 97%

MDL
MFCD00009064
EINECS
219-843-2

Chemical Properties

Formula
C9H20O3Si
Formula Weight
204.34
Boiling Point
176-177°
Flash Point
21°(69°F)
Density
0.953
Refractive Index
1.4070
Sensitivity
Moisture Sensitive
Solubility
Hydrolyzes in water.

Applications

Allyltriethoxysilane is used as chemical additives and intermediates. It is used as general catalyst.

Notes

Moisture Sensitive. Store away from oxidizing agents. Incompatible with moisture and oxidizing agents.

Literature References

Shingo Yamasaki; Kunihiko Fujii; Reiko Wada; Motomu Kanai and Masakatsu Shibasaki. A General Catalytic Allylation Using Allyltrimethoxysilane.J. Am. Chem. Soc.2002, 124 (23), 6536-6537.

Ying-Sing Li; Nicolas E. Vecchio; Yu Wang; Cheneel McNutt. Vibrational spectra of metals treated with allyltrimethoxysilane sol-gel and self-assembled monolayer of allytrichlorosilane..Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.2007, 67 598-603.

Phosphine-free Heck reaction with aryldiazonium fluoroborates, catalyzed by Pd(OAc)2, affords symmetrically coupled trans-stilbenes, generally in good yields; the presence of various functionalities, e.g. iodo, nitro or methoxycarbonyl, is tolerated: J. Chem. Soc., Perkin 1, 275 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1772306
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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