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L04503 N,N-Diethylformamide, 99%

CAS Number
617-84-5
Synonyms

Stock No. Size Price ($) Quantity Availability
L04503-22 100g 73.40
L04503-36 500g 313.00
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N,N-Diethylformamide, 99%

MDL
MFCD00003287
EINECS
210-533-2

Chemical Properties

Formula
HCON(CH2CH3)2
Formula Weight
101.15
Boiling Point
178°
Flash Point
65°(149°F)
Density
0.910
Refractive Index
1.4340
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with acetone, benzene, alcohol and ether.  

Applications

N,N-Diethylformamide is used in the synthesis of metal-organic frameworks and Diethyltrifluoromethylamine. It is also used as solvent in the preparation of porous cubic-shaped zinc oxide particles. It is involved in the preparation of quinazoline-2,4(1H,3H)-dione by reacting with o-aminonitrile.

Notes

Incompatible with strong oxidizing agents. Avoid heat, flames and spark.                      

Literature References

Zhang, Y. B.; Furukawa, H.; Ko, N.; Nie, W.; Park, H. J.; Okajima, S.; Cordova, K. E.; Deng, H.; Kim, J.; Yaghi, O. M. Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal-Organic Framework-177. J. Am. Chem. Soc. 2015, 137 (7), 2641-2650.

Iranpoor, N.; Firouzabadi, H.; Rizi, Z. T.; Erfan, S. WCl6/DMF as a new reagent system for the phosphine-free Pd (0)-catalyzed aminocarbonylation of aryl halides. RSC Adv. 2014, 4 (81), 43178-43182.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1209392
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2924.19
TSCA
Yes
RTECS
LQ1925000

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