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5296-64-0 - Allyl phenyl sulfide, 97% - L04771 - Alfa Aesar

L04771 Allyl phenyl sulfide, 97%

CAS Number
5296-64-0
Synonyms

Size Price ($) Quantity Availability
10g 59.60
50g 231.00
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Allyl phenyl sulfide, 97%

MDL
MFCD00014957
EINECS
226-142-5

Chemical Properties

Formula
C9H10S
Formula Weight
150.24
Boiling Point
223-225°
Flash Point
>98°(208°F)
Density
1.024
Refractive Index
1.5740

Literature References

The lithiated derivative can react with electrophiles at either the ɑ- or - postion. It was found that conversion of the organolithium to an organotitanium reagent, by reaction with Ti(O-iPr)4, followed by reaction with e.g. cyclohexanecarboxaldehyde resulted in regioselective reaction at theɑ-position to give the corresponding hydroxy sulfide: Bull. Chem. Soc. Jpn., 57, 2781 (1984). For review of allylic and benzylic carbanions substituted by heteroatoms, see: Org. React., 27, 1 (1982).

/n

Grignard reagents can be allylated with allylic sulfides in the presence of a Ni or Pd catalyst: Tetrahedron Lett., 3425 (1979).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P261-P280h

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing.

Other References

Beilstein
1856940
Harmonized Tariff Code
2930.90
TSCA
No

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