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Knoevenagel condensation occurs with aromatic aldehydes. Attempted hydrolysis with base results in reversal of the condensation reaction, but decarboethoxylation can be achieved by treatment with LiI in DMF, providing a useful synthesis of arylvinyl methyl sulfones: Synthesis, 806 (1980):/n
Hazard Statements: H315-H319
Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P260-P201-P280g-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.