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776-99-8 - 3,4-Dimethoxyphenylacetone, 97% - 1-(3,4-Dimethoxyphenyl)-2-propanone - Methyl veratryl ketone - L05477 - Alfa Aesar

L05477 3,4-Dimethoxyphenylacetone, 97%

CAS Number
776-99-8
Synonyms
1-(3,4-Dimethoxyphenyl)-2-propanone
Methyl veratryl ketone

Size Price ($) Quantity Availability
10g 35.43
50g 92.00
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3,4-Dimethoxyphenylacetone, 97%

MDL
MFCD00008772
EINECS
212-285-0

Chemical Properties

Formula
C11H14O3
Formula Weight
194.23
Boiling Point
154-158°/12mm
Flash Point
>110°(230°F)
Density
1.115
Refractive Index
1.5358
Solubility
Insoluble in water.

Applications

3,4-Dimethoxyphenylacetone was used as starting material in the synthesis of α-methyl-dopa, an important nonproteogenic α-amino acid for pharmaceutical applications. 3,4-Dimethoxyphenylacetone undergoes asymmetric amination catalyzed by Brevibacterium linens IFO 12141 strain to yield corresponding optically active amine

Notes

Stable under normal temperatures and pressures. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.

Literature References

W H Boesten et. al. Asymmetric strecker synthesis of alpha-amino acids via a crystallization-induced asymmetric transformation using (R)-phenylglycine amide as chiral auxiliary. Organic letters. 2001, 3,(8), 1121-1124.

Nakamichi K, et al. Asymmetric amination of 4-methoxyphenylacetone and its related compounds with microorganisms. Appl. Microbiol. Biotechnol. 1990, 33,(6), 637-640.

Other References

Beilstein
1107410
Harmonized Tariff Code
2914.50
TSCA
No
RTECS
UC1795500

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