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Reagent used in the protection of amino groups as their N-dithiasuccinimide (Dts) derivatives: J. Org. Chem., 42, 2819 (1977). The group is stable to acid but is cleaved by treatment with a thiol, e.g. 2-mercaptoethanol and base: J. Am. Chem. Soc., 99, 7363 (1977); 102, 3084 (1980). For use in the protection of amino sugars, including selective reduction in the presence of an azido group with sodium borohydride, see: J. Chem. Soc., Perkin 1, 405 (1995). See also Appendix 6./n
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.