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2757-23-5 - Chlorocarbonylsulfenyl chloride, 97% - Chloroformylsulfenyl chloride - L06432 - Alfa Aesar

L06432 Chlorocarbonylsulfenyl chloride, 97%

CAS Number
2757-23-5
Synonyms
Chloroformylsulfenyl chloride

Size Price ($) Quantity Availability
1g 26.10
5g 65.90
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Chlorocarbonylsulfenyl chloride, 97%

MDL
MFCD00000703
EINECS
220-415-2

Chemical Properties

Formula
CCl2OS
Formula Weight
130.98
Boiling Point
98-101°
Density
1.580
Refractive Index
1.5170
Sensitivity
Moisture Sensitive

Literature References

Reagent used in the protection of amino groups as their N-dithiasuccinimide (Dts) derivatives: J. Org. Chem., 42, 2819 (1977). The group is stable to acid but is cleaved by treatment with a thiol, e.g. 2-mercaptoethanol and base: J. Am. Chem. Soc., 99, 7363 (1977); 102, 3084 (1980). For use in the protection of amino sugars, including selective reduction in the presence of an azido group with sodium borohydride, see: J. Chem. Soc., Perkin 1, 405 (1995). See also Appendix 6.

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GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
506318
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2930.90
TSCA
No

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