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1629-58-9 - Ethyl vinyl ketone, 97%, stab. - 1-Penten-3-one - L06829 - Alfa Aesar

L06829 Ethyl vinyl ketone, 97%, stab.

CAS Number
1629-58-9
Synonyms
1-Penten-3-one

Size Price ($) Quantity Availability
5g 43.26
25g 163.77
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Ethyl vinyl ketone, 97%, stab.

MDL
MFCD00009316
EINECS
216-624-3

Chemical Properties

Formula
C5H8O
Formula Weight
84.12
Boiling Point
103-104°
Flash Point
-6°(21°F)
Density
0.844
Refractive Index
1.4200
Solubility
Insoluble in water; soluble in most organic solvents.

Applications

Ethyl vinyl ketone is used as reagent for annulation.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and heat.

Literature References

Min Shi; Guang-Ning Ma; Jun Gao. Chiral bifunctional organocatalysts in asymmetric aza-Morita-Baylis-Hillman reactions of ethyl (arylimino) acetates with methyl vinyl ketone and ethyl vinyl ketone. J. Org. Chem. 2007, 72,(25), 9779-9781.

 

Harold W.Gardner; Marilyn J.Grove; Yangkyo P.Salch. Enzymic pathway to ethyl vinyl ketone and 2-pentenal in soybean preparations. J. Agric. Food Chem. 1996, 44,(3), 882-886.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H300-H310-H330-H314-H318

Highly flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1735857
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2914.19
TSCA
Yes
RTECS
SB3800000

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