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Ethyl vinyl ketone is used as reagent for annulation.
Min Shi; Guang-Ning Ma; Jun Gao. Chiral bifunctional organocatalysts in asymmetric aza-Morita-Baylis-Hillman reactions of ethyl (arylimino) acetates with methyl vinyl ketone and ethyl vinyl ketone. J. Org. Chem. 2007, 72,(25), 9779-9781.
Harold W.Gardner; Marilyn J.Grove; Yangkyo P.Salch. Enzymic pathway to ethyl vinyl ketone and 2-pentenal in soybean preparations. J. Agric. Food Chem. 1996, 44,(3), 882-886.
Hazard Statements: H225-H300-H310-H330-H314-H318
Highly flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a
IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.