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L06941 Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%

CAS Number
175136-62-6
Synonyms

Stock No. Size Price ($) Quantity Availability
L06941-MD 250mg 45.10
L06941-03 1g 125.00
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Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%

MDL
MFCD00042428

Chemical Properties

Formula
C24H9F18P
Formula Weight
670.28
Melting point
98-102°
Boiling Point
128-130°/0.5mm
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Tris[3,5-bis(trifluoromethyl)phenyl]phosphine is used as ligands which is useful as catalysts in various reactions.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Shin-ichiro Fujita; Shinya Fujisawa; Bhalchandra M.Bhanage; Masahiko Arai. Rhodium-tris(3,5-bis(trifluoromethyl)phenyl)phosphine catalyzed hydroformylation of dienes to dialdehydes in supercritical carbon dioxide with high activity. Tetrahedron Letters. 2004, 45,(6), 1307-1310.

 

Tatsuo Ishiyama; Hironori Isou; Takao Kikuchi; Norio Miyaura. Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes. Chem. Commun. 2010, 46,(1), 159-161.

In a study of coupling reactions in supercritical CO2, catalyzed by Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tri(2-furyl)­phosphine, L13329, Tris(pentafluorophenyl)­phosphine, L02748

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
6556841
Harmonized Tariff Code
2931.39
TSCA
No

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