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5911-08-0 - (Chloromethyl)cyclopropane, 97% - Cyclopropylmethyl chloride - L06986 - Alfa Aesar

L06986 (Chloromethyl)cyclopropane, 97%

CAS Number
5911-08-0
Synonyms
Cyclopropylmethyl chloride

Size Price ($) Quantity Availability
5g 63.00
25g 237.60
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(Chloromethyl)cyclopropane, 97%

MDL
MFCD00001307
EINECS
227-632-1

Chemical Properties

Formula
C4H7Cl
Formula Weight
90.55
Melting point
-91°
Boiling Point
87-89°
Flash Point
-1°(30°F)
Density
0.980
Refractive Index
1.4360
Solubility
Not miscible in water.

Applications

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.

Literature References

V.F.Kalasinsky; C. J.Wurrey. Vibrational spectra and conformations of (chloromethyl)cyclopropane and epichlorohydrin. Journal of Raman Spectroscopy. 1980, 9,(5), 315-323.

 

N.Heineking; J.U.Grabow; I.Merke. Molecular beam Fourier transform microwave spectra of (chloromethyl)cyclopropane and (chloromethyl)oxirane. Journal of Molecular Structure. 2002, 612,(2-3), 231-244.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H315-H319-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280h-P243-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
635697
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.89
TSCA
No

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