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Methyl 4-chloro-3-nitrobenzoate, is used as starting material for the preparation of the methyl benzoates
M. K. ChantooniJr.; I. M. Kolthoff. Resolution of acid strength in tert-butyl alcohol and isopropyl alcohol of substituted benzoic acids, phenols, and aliphatic carboxylic acids. Anal. Chem. 1979, 51, (1), 133-140.
Joseph Miller. The SN Mechanism in Aromatic Compounds. VI. Carbonyl and Nitrile Substituents. J. Am. Chem. Soc. 1954, 76, (2), 448-450.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.