Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

L07557 Vinylacetic acid, 96%

CAS Number
625-38-7
Synonyms
3-Butenoic acid

Stock No. Size Price ($) Quantity Availability
L07557-14 25g 95.10
L07557-22 100g 293.00
Add to Cart Bulk/Specialty Print Quote View Item

Vinylacetic acid, 96%

MDL
MFCD00002782
EINECS
210-892-5

Chemical Properties

Formula
C4H6O2
Formula Weight
86.09
Melting point
-39°
Boiling Point
162-163°
Flash Point
65°(149°F)
Density
1.012
Refractive Index
1.4240
Storage & Sensitivity
Keep Cold.
Solubility
Fully miscible.

Applications

Vinylacetic acid used in the preparation of strained nitroso Diels-Aldrer adducts which undergo a domino ROC metathesis in the presence of Ru-carbene catalysts and olefins. It is used in the synthesis of polyethylene glycolated boltorn coatings. It was used to study the inhibition of the enzyme-catalyzed conversion of D-tyrosyl- phenylalanyl-glycine to D-tyrosyl-phenylaline amide by non-peptide carboxylic acids.

Notes

Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with oxidizing agents, heat, Bases, Reducing agents.

Literature References

Marco Laurenti; Pablo Guardia; Rafael Contreras-Cáceres; Jorge Pérez-Juste; Antonio Fernandez-Barbero; Enrique Lopez-Cabarcos; Jorge Rubio-Retama. Synthesis of thermosensitive microgels with a tunable magnetic core.Langmuir.2011, 27 (17), 10484-10491.

A F Bradbury; J Mistry; B A Roos; D G Smyth. 4-Phenyl-3-butenoic acid, an in vivo inhibitor of peptidylglycine hydroxylase (peptide amidating enzyme).European Journal of Biochemistry.1990, 189 (2), 363-368.

ß-Unsaturated acids, including vinylacetic acid, undergo bromolactonization with bromine in the presence of bicarbonate giving a mixture of ß- and -lactones: J. Org. Chem., 55, 2487 (1990). Further treatment of the lactone mixture with AgNO3 in acetic acid provides a route to butenolides: Tetrahedron Lett., 34, 1411 (1993).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H314-H335

Combustible liquid. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1699159
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2916.19
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware