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Vinylacetic acid used in the preparation of strained nitroso Diels-Aldrer adducts which undergo a domino ROC metathesis in the presence of Ru-carbene catalysts and olefins. It is used in the synthesis of polyethylene glycolated boltorn coatings. It was used to study the inhibition of the enzyme-catalyzed conversion of D-tyrosyl- phenylalanyl-glycine to D-tyrosyl-phenylaline amide by non-peptide carboxylic acids.
Marco Laurenti; Pablo Guardia; Rafael Contreras-Cáceres; Jorge Pérez-Juste; Antonio Fernandez-Barbero; Enrique Lopez-Cabarcos; Jorge Rubio-Retama. Synthesis of thermosensitive microgels with a tunable magnetic core.Langmuir.2011, 27 (17), 10484-10491.
A F Bradbury; J Mistry; B A Roos; D G Smyth. 4-Phenyl-3-butenoic acid, an in vivo inhibitor of peptidylglycine hydroxylase (peptide amidating enzyme).European Journal of Biochemistry.1990, 189 (2), 363-368.
ß-Unsaturated acids, including vinylacetic acid, undergo bromolactonization with bromine in the presence of bicarbonate giving a mixture of ß- and -lactones: J. Org. Chem., 55, 2487 (1990). Further treatment of the lactone mixture with AgNO3 in acetic acid provides a route to butenolides: Tetrahedron Lett., 34, 1411 (1993).
Hazard Statements: H227-H302-H314-H335
Combustible liquid. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.
Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant